|
No
|
Date |
Topics
|
Chapter in Klein
|
PowerPoint or
Models |
| 1 |
8/22 |
The
structural theory. Lewis and line-bond
structures.
|
1
|
|
| 2 |
8/24 |
Drawing
line-bond structure by reference to normal
valencies of elements. Formal Charge.
|
1
|
|
| 3 |
8/26 |
Isomerism. Review of VSEPR
Theory and Molecular Polarity.
|
1
|
|
| 4 |
8/29 |
Valence bond theory. Hybrid
orbitals. Pi and Sigma bonds.
|
1
|
|
| 5 |
8/31 |
Intermolecular forces and
physical properties.Constitutonal isomers.
|
1
|
|
| 6 |
9/2 |
Functional group families. Condensed and
skeletal structures. Naming alkanes and
finding isomers.
|
2, 4
|
|
| 7 |
9/7 |
Acid/base
reactions. Predicting acidity.
|
2, 3
|
|
| 8 |
9/9 |
Resonance and its
effect on acidity.Inductive
effects on acidity.
|
3
|
|
| 9 |
9/12 |
C-13
NMR
|
16
|
|
| 10 |
9/14 |
Alkane naming, branched alkyl groups, cycloalkanes and bicyclic alkanes.
|
4
|
|
| 11 |
9/16 |
Conformations
of substituted cyclohexanes. Cis/trans isomerism.
|
4
|
|
| 12 |
9/19 |
Proton
NMR.
|
16
|
|
| 13 |
9/21 |
Acids and bases. Part II. Practical aspects. |
3
|
|
| 13 |
9/23 |
Exam
1
Key: Version A p2, p3, p4, p5
Version B p2, p3, p4, p5
|
1-4, 16
|
|
| 14 |
9/26 |
Equilibrium
constants and rates. Energy diagrams.
|
6
|
|
| 15 |
9/28
|
Kinetics
and Collision Theory. Transition State
Theory.
|
6
|
|
| 16 |
9/30 |
Mechanisms
and arrow pushing.
|
6
|
|
| 17 |
10/3 |
Stereoisomerism and naming of alkenes; cis/trans vs E/Z designations.
|
5.1, 8.3, 8.4
|
|
| 18 |
10/5
|
Mechanisms
of nucleophilic substitution. SN2
and SN1 mechanisms. Kinetics.
|
5
|
|
| 19 |
10/7 |
Properties
of enantiomers. Optical activity and specific rotation. Racemic
mixtures, chiral non-racemic, and achiral
compounds. Stereochemistry of SN2 reactions.
|
7
|
|
| 20 |
10/10 |
SN2
- Effect of R group on rate; steric
hindrance. Effect of leaving group ability. Effect of nucleophile.
|
7
|
|
| 21 |
10/12 |
Solvent effects in SN2 reactions and SN1 reactions.
|
7
|
|
| 22 |
10/14 |
SN1 reactions. Effect of carbocation stability. Stereochemistry.
|
7
|
|
| 23 |
10/17 |
Carbocation rearrangements.
|
7
|
|
| 24 |
10/19 |
Predicting SN2 or SN1
mechanism. SN2 reactions in
synthesis.
|
7
|
|
| |
10/21 |
|
5-7, 15 (IR), 16 (H NMR)
|
|
| 25 |
10/24 |
Mass spectrometry. Diisoptopic elements, the nitrogen rule, types of fragmentation reactions. |
15
|
|
| 26 |
10/26 |
1,2-Elimination
of Alkyl Halides. The E1, E2, and E1cb
mechanisms. E2 reactions and Zaitsev's
rule.
|
8
|
|
| 27 |
10/28 |
Stereochemistry of E2
reactions. Bulky bases
used for E2 reactions.
|
8
|
|
| 28 |
10/31 |
The
E1 mechanism. Predicting the reaction and
mechanism. SN2, E2, or SN1/E1.
Preparation of alkynes by E2. |
8
|
|
| 29 |
11/2 |
Addition of HX and X2
to alkenes. Stereochemistry of HX and X2addition. |
9
|
|
| 30 |
11/4 |
Hydration of alkenes. |
9
|
|
| 31 |
11/7 |
Oxidation of alkenes. |
9
|
|
|
11/9 |
Exam 3
|
8-9, 15 (MS)
|
|
32
|
11/12 |
Alkynes
|
10
|
|
| 33 |
11/14 |
Alkynes
|
10
|
|
| 34 |
11/16 |
Alkynes
|
10
|
|
| 35 |
11/18 |
Alkynes |
10
|
|
| 36 |
11/21 |
Radical
Reactions |
11
|
|
| 37 |
11/28 |
Radical
Reactions
|
11
|
|
| 38 |
11/30 |
Radical
Reactions
|
11
|
|
| 39 |
12/2 |
Radical Reactions |
11
|
|
|
12/5
|
Exam 4 |
10-11
|
|
